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TRANSLATION OF DOC. NO. NI 9912 Office of Chief of
Counsel for War Crimes |
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DIRECTIVES FOR THE USE OF PRUSSIC ACID (ZYKLON
FOR THE DESTRUCTION OF VERMIN
(DISINFESTATION) |
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I. |
Properties of prussic acid (hydrocyanic
acid) |
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Prussic acid is a gas which is generated by
evaporation. Boiling point 25 degrees Centigrade Freezing
point -15 degrees Centigrade Specific gravity 0.69 Steam
density 0.97 (Air 1.0) The liquid evaporates easily Liquid:
Transparent, colourless Smell: Peculiar, repulsively sweet
Extraordinarily great penetrative powers Prussic acid is
soluble in water |
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Danger of explosion |
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At 75 g prussic acid per m3 air. (Normal application
approx. 8 10 g per m3, therefore not explosive.) Prussic
acid may not be brought into contact with an open flame, glowing
wires etc., because then burns up slowly and loses all its
effectiveness (carbonic acid, water and nitrogen are formed)
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Toxic effects on warm blooded animals
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Since prussic acid has practically no indicative
irritant effect it is highly toxic and very dangerous. Prussic
acid is one of the most powerful poisons. 1mg per kg of body weight
is sufficient to kill a human being. Women and children are
generally more susceptible than men. Very small amounts of
prussic acid do not harm the human body, even if breathed
continuously. Birds and fishes are particularly susceptible to
prussic acid. |
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Toxic effects on insects |
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The effects of prussic acid on insects do not depend
on the temperature to the same extent as that of other gases,
that is, it is also effective at low temperatures (even at 5
degrees Cent.) The eggs of many insects, particularly of bugs
and lice, are more susceptible than the full grown insects.
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Toxic effects on plants |
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The degree of toxicity depends on the type of
vegetation on the plants. Plants with thick leaves are less
susceptible than those with thin ones. Mildew and dry rot are not
killed by prussic acid. Prussic acid does not destroy bacteria.
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II |
Method of using prussic acid |
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ZYKLON is the absorption of a mixture of prussic acid
and an irritant by a carrier. Wood fiber discs, a reddish brown
granular mass (Diagriess Dia gravel) or small blue cubes (Erco)
are used as carriers. |
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Apart from serving its purpose as an indicator, this
irritant also has the advantage of stimulating the respiration
of insects. Prussic acid and the irritant are generated through
simple evaporation. Zyklon will keep for 3 months. Use damaged
cans first. The contents of a can must be used up at once.
Liquid prussic acid damages polish, lacquer, paint etc. Gaseous
prussic acid is harmless. The toxicity of the prussic acid
remains unchanged by the addition of the irritant; the danger
connected with it is however considerably decreased. |
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Zyklon can be rendered [harmless] by
combustion. |
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III |
Possible poisoning |
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1. |
Slight poisoning
Dizziness headache,
vomiting, general feeling of sickness, etc,. All these symptoms pass
if one immediately gets out into the fresh air. Alcohol reduces
resistance to prussic acid gassing, therefore do not drink
alcohol before fumigation.
Prescribe 1 tablet Cardiazol or
Veriazol in order to prevent heart disorders, if necessary
repeat after 2-3 hours. |
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2. |
Severe poisoning
The affected
person will collapse suddenly and faint
First aid: fresh
air, remove gas mask, loosen clothing, apply artificial respiration.
Lobelin, intramuscular 0.01g. Do not give camphor injections.
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3. |
Poisoning through the skin
Symptoms as
for 1. Treat in the same way. |
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4. |
Stomach poisoning
Treat with Lobelin
intramuscular 0.01 g Ferrous sulfate Burnt
magnesia. |
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IV |
Protection against gas
When fumigating
with Zyklon use only special filters, e.g the filter insert "J"
(blue brown) of the Auergesellschaft Berlin or of the
Draegewerke, Luebeck. Should gas seep through the mask, leave the
building immediately and change filters after also checking the
mask and its fit to see whether they are
tight |